1-{2-[(2,4-Dichlorobenzylidene)amino]ethyl}-3-methylimidazolium hexafluorophosphate

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Liquid structure of 1-butyl-3-methylimidazolium hexafluorophosphate by neutron diffraction with H/D isotopic substitution method.

The liquid structure of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate, [BMIM]PF(6), was investigated by neutron diffraction with H/D substitution method, where the hydrogen atoms in the imidazolium ring were partially deuterated. The local structures around the ring hydrogen atoms in liquid are very similar to those estimated from the crystal structure.

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Transport properties of binary mixtures of carbon dioxide and 1-butyl-3-methylimidazolium hexafluorophosphate studied by transient grating spectroscopy.

Transient grating spectroscopy was applied to measurements of sound velocity and thermal diffusivity in binary mixture solutions of carbon dioxide (CO(2)) and 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIm][PF(6)]) along the saturated line of CO(2) at 40 degrees C up to 20.0 MPa. The sound velocity decreased more than 10% by increasing the pressure to 10 MPa, and the pressure effect was...

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1-{2-[(2-hydroxybenzylidene)-amino]-ethyl}-3-methyl-3H-imidazolium hexafluorophosphate

The title Schiff base compound, C(13)H(16)N(3)O(+)·PF(6) (-), was derived from the condensation of 2-hydroxy-benaldehyde with the ionic liquid 1-(2-amino-ethyl)-3-methyl-imidazolium hexa-fluoro-phosphate in an ethanol solution. The asymmetric unit comprises one cation and two PF(6) (-) anions. The dihedral angle between the aromatic and imidazole rings is 15.2 (2)°. An intra-molecular O-H⋯N hyd...

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Effects of Solubilized Water on the Relaxation Dynamics Surrounding 6-Propionyl-2-(N,N-dimethylamino)naphthalene Dissolved in 1-Butyl-3-methylimidazolium Hexafluorophosphate at 298 K

We report on the picosecond time-resolved fluorescence of 6-propionyl-2-(N,N-dimethylamino)naphthalene (PRODAN) dissolved in 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) at 298 K as a function of solubilized water in the [bmim][PF6] phase. The observed solvent relaxation dynamics can be described by three components with apparent relaxation times that occur over a large time re...

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Uultra-trace determination of cadmium (II) in aqueous environmental samples by a new ion selective electrode based on nefazodone and 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid

Background and Objective: Cadmium is a potential environmental contaminant that causes adverse effects on the environment and the health of living organisms. Therefore, designing a simple and economic technique for its determination is very important. In this respect, a potentiometric sensor based on nefazodone as the ionophore and [BMIM]PF6 as the ionic additive were developed for the determin...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809045115